Steady-state drawing of polymer melts

Nonlocal viscosity of polymer melts approaching their glassy state.

The nonlocal viscosity kernels of polymer melts have been determined by means of equilibrium molecular dynamics upon cooling toward the glass transition. Previous results for the temperature dependence of the self-diffusion coefficient and the value of the glass transition temperature are confirmed. We find that it is essential to include the attractive part of the interatomic potential in orde...

Properties of Confined Polymer Melts

Properties of simple models of confined linear polymer chains were studied by means of the Monte Carlo method. Model chains were built of united atoms (statistical segments) and embedded to a simple cubic lattice. Then polymers were put into a slit formed by two parallel impenetrable surfaces. Chain lengths were varied up to 800 segments and the density of the polymer melt was changed up to 0.5...

Nanoparticle Dynamics in Polymer Melts

Reaction Kinetics in Polymer Melts

We study the reaction kinetics of end-functionalized polymer chains dispersed in an unreactive polymer melt. Starting from an infinite hierarchy of coupled equations for many-chain correlation functions, a closed equation is derived for the 2nd order rate constant k after postulating simple physical bounds. Our results generalize previous 2-chain treatments (valid in dilute reactants limit) by ...

Steady State Analysis of Nanofuel Droplet ‎Evaporation

The potential for nanofuels as one of the clean sources of energy on account of its enhanced combustion performance coupled with low emissions has been established. Considering the importance of the fuel evaporation phase in the entire combustion process, this work presents an attempt at applying the steady state analysis equations to nanofuel experimental data obtained from the li...